The dynamic characteristics of polyurethane matrix of dye laser solid-state active elements

Authors

  • Ludmila Kosyanchuk
  • Nataly Kozak Department of polymer physics Institute of Macromolecular Chemistry NAS of Ukraine
  • Natalia Babkina
  • Volodymyr Bezrodnyy
  • Marina Stratilat

DOI:

https://doi.org/10.17721/fujcV4I2P40-46

Keywords:

polyurethane, phenalenone dye, laser damage threshold, paramagnetic probe, radiation resistance

Abstract

Investigations of polyurethane matrices for solid-state laser active elements showed that comparison of chain mobility and permeability for low molecular substances of polyurethanes based on glycol and diisocyanate components of various structures allows predict their radiation resistance and choose optimal chemical composition of polyurethane. The correlation was shown of polyurethane dynamic properties with values of their elastic modulus and laser damage threshold under pulsed laser irradiation as well as the weak influence of phenalenone dyes introduction on the above characteristics.

References

Zemskyi VA, Kolesnikov YuL, Meshkovskyi IK. Fizika i tekchnica impulsnykh lazerov na krasitelyakh (Physics and technology of pulsed dye lasers). SPB SPbGU ITMO 2005;:176.

Ishchenko A, Grabchuk G. Physical and chemical problems of the creation of photostable converters of light energy on the basis of dyed polymers. Theoretical and Experimental Chemistry 2009;45(3):143-167. https://doi.org/10.1007/s11237-009-9078-5

Duarte F. Solid-state multiple-prism grating dye-laser oscillators. Appl. Opt. 1994;33(18):3857. https://doi.org/10.1364/ao.33.003857

Gromov D, Dyumaev K, Manenkov A, Maslyukov A, Matyushin G, Nechitailo V, Prokhorov A. Efficient plastic-host dye lasers. Journal of the Optical Society of America B 1985;2(7):1028. https://doi.org/10.1364/josab.2.001028

Maslyukov A, Sokolov S, Kaivola M, Nyholm K, Popov S. Solid-state dye laser with modified poly(methyl methacrylate)-doped active elements. Appl. Opt. 1995;34(9):1516. https://doi.org/10.1364/ao.34.001516

Kosyanchuk L, Bezrodna T, Stratilat M, Menzheres G, Kozak N, Todosiichuk T. Peculiarities of interactions between 6-aminophenalenone dye and polyurethane matrix. Journal of Polymer Research 2014;21(10):1-7. https://doi.org/10.1007/s10965-014-0564-7

Bezrodnyi V, Negryiko A, Klishevich G, Stratilat M, Kosyanchuk L, Todosiichuk T. Investigations of photophysical and generation properties of active elements based on dyes in aliphatic polyurethane matrix. Journal of Polymer Research 2013;20(9):1-8. https://doi.org/10.1007/s10965-013-0246-x

Bezrodnyi V, Ishchenko A. Laser media based on coloured polyurethane. Quantum Electronics 2000;30(12):1043-1048. https://doi.org/10.1070/qe2000v030n12abeh001862

Kosyanchuk L, Stratilat M, Kozak N, Todosiichuk T. The influence of the phenalenone dyes on the kinetics of the polyurethanes formation with different nature of the diisocyanate unit. Polim. J. 2015;37(3):235-240.

Kovarskii AL. Spin probes and labels. A quarter of a century of application to polymer studies, In: Pethrick R.A. editor. Polymer Yearbook 1996;13:113‐139.

Kosyanchuk L, Stratilat M, Kozak N, Todosiichuk T. Influence of diisocyanate component nature of polyurethanes doped with phenalenone dyes on rotational dynamics of nitroxyl paramagnetic probe. Ukr Chem J 2015;81(1):56-61.

Luo R, Gilson H, Potter M, Gilson M. The Physical Basis of Nucleic Acid Base Stacking in Water. Biophysical Journal 2001;80(1):140-148. https://doi.org/10.1016/s0006-3495(01)76001-8

Downloads

Published

2016-12-27

Issue

Section

Articles