Ionic liquids in catalysis: molecular and nanometric metal systems

Authors

  • Gustavo Chacón Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, Université de Toulouse 3 – Paul Sabatier, 118 route de Narbonne, 31062 Toulouse cedex 9, France Current address: Institute of Chemistry, Laboratory of Molecular Catalysis UFRGS, Av. Bento Gonçalves, 9500, 91501-970 P.O. Box 15003, Porto Alegre, RS, Brazil
  • Jérôme Durand Laboratoire de Chimie de Coordination, UPR CNRS 8241 composante ENSIACET, Université de Toulouse, 4 allée Emile Monso-CS 44362, 31030 Toulouse cedex 4, France
  • Isabelle Favier Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, Université de Toulouse 3 – Paul Sabatier, 118 route de Narbonne, 31062 Toulouse cedex 9, France
  • Emmanuelle Teuma Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, Université de Toulouse 3 – Paul Sabatier, 118 route de Narbonne, 31062 Toulouse cedex 9, France
  • Montserrat Gomez Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069 Université de Toulouse 3 - Paul Sabatier

DOI:

https://doi.org/10.17721/fujcV4I1P23-36

Keywords:

ionic liquids, catalysis, organometallic complexes, metallic nanoparticles, supported ionic liquid phase

Abstract

The catalyst immobilization in a liquid phase represents an attractive means to preserve high activities and selectivities, also permitting an easy recycling. To attain this goal, organic products should be extracted in a simple way from the catalytic phase leading to metal-free target compounds; for this reason, ionic liquids exhibiting high affinity for metallic species and low affinity for low polar compounds, turn into a promising medium, in particular for the synthesis of fine chemicals. In the present Accounts, we illustrate this approach through our research involving both molecular organometallic compounds and metallic nanoparticles dispersed in an ionic liquid phase.

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Chacón G, Madec D, Gómez M. under submission.

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Published

2016-05-31

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Vol. 4 No. 1 (2016): Ionic Liquids: from Neoteric Solvents to New Materials

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