Aromatic Structure Influence on the Selectivity of Substituted Methacryloylaminophenylmethacrylates Free-Radical Polymerization

L. O. Vretik, O. A. Nikolaeva, V. V. Zagniy, V. G. Syromyatnikov

Abstract


A new dimethacrylic monomer with biphenylbenzoate-type aromatic core was tested to the possibility to carry out its selective homopolymerization under conditions of thermoinitiated radical polymerization in DMF solution. The kinetics of thermo-induced radical homopolymerization of this monomer as well as some model compounds were studied by dilatometry. The preferring polymerization of O-methacryloyl double bond was proved by 1H NMR spectroscopy.

Keywords


methacryloylaminophenylmethacrylates; radical polymerization

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References


Syromyatnikov V, Vretik L, Yaroshchuk O, Zakrevskyy Y, Kim T, Jo J, Kim J, Kim S. Naphthalene Containing Polymers as New Photoaligning Materials for LCs. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 2001;368(1):543-549. https://doi.org/10.1080/10587250108029986

Vretik L, Syromyatnikov V, Zagniy V, Paskal L, Yaroshchuk O, Dolgov L, Kyrychenko V, Lee C. Polymethacryloylaminoarylmethacrylates: New Concept of Photoalignment Materials for Liquid Crystals. Molecular Crystals and Liquid Crystals 2007;479(1):121/[1159]-134/[1172]. https://doi.org/10.1080/15421400701680846

Kyrychenko V, Smolyakov G, Zagniy V, Vretik L, Paskal L, Syromyatnikov V, Yaroshchuk O. Photochemistry of Bis-Methacrylic Polymers and Alignment of Liquid Crystals. Molecular Crystals and Liquid Crystals 2008;496(1):278-292. https://doi.org/10.1080/15421400802451873

Odian G. Principles of Polymerization, 4th ed., Wiley: Hoboken 2004, 490. https://doi.org/10.1002/047147875x

Lipatov YuS, Nesterov AE, Gritsenko TM, Veselovskiy RA. Guide to polymer chemistry K.: Naukova dumka. 1971, 536 p.

Paskal LP. Syntheses and investigation of new photosensitive monomers based on aminophenols. Thesis for the Candidate of chemical sciences degree. Kyiv 1984, 185 p.

Paskal LP, Syromyatnikov VG, Kalmykova TA. Visnyk Kyivs’kogo Universytetu 1978;19:45-49


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