Corrosion Inhibition, Adsorption and Thermodynamic Properties of Poly (Sodium 4-Styrenesulfonate) on Carbon Steel in Phosphoric Acid Medium
Keywords:Poly (sodium 4-styrenesulfonate), Adsorption mechanism, thermodynamic parameters, SEM, DFT
The use of polymers as corrosion inhibitors has attracted much attention due to their low prices, inherent stability, availability and cost-effectiveness. The corrosion inhibiting effect of poly(sodium-4-styrenesulfonate) on carbon steel in phosphoric acid solution has been investigated using weight loss and scanning electron microscopy techniques (SEM) and theoretical calculations based on density functional theory (DFT). In the presence of 1.0×10-3 mol/L of inhibitor, a maximum inhibition effect of 98.06 % was observed. The influence of the concentration of the inhibitor, the temperature of the solution and the immersion time on the corrosion of carbon steel was investigated. Activation parameters such as activation energy (Eact), activation enthalpy (ΔHact), activation entropy (ΔSact), heat of adsorption (Qads) and adsorption free energy (ΔGads) were evaluated based on the effect of temperature on the corrosion and inhibition processes. It was found that the adsorption behaviour of poly(sodium-4-styrenesulfonate) (PSS) follows the Langmuir isotherm and the free energy change values indicate mixed chemical and physical adsorption on the carbon steel surface. The results obtained with the different methods agree well.
Abeng FE, Ikpi ME, Anadebe VC, Emori W. Metolazone compound as corrosion inhibitor for API 5L X-52 steel in hydrochloric acid solution. Bulletin of the Chemical Society of Ethiopia 2020;34(2):407-418. https://doi.org/10.4314/bcse.v34i2.16
Attar T, Benchadli A, Messaoudi B, Benhadria N, Choukchou-Braham E. Experimental and Theoretical Studies of Eosin Y Dye as Corrosion Inhibitors for Carbon Steel in Perchloric Acid Solution. Bulletin of Chemical Reaction Engineering & Catalysis 2020;15(2):454-464. https://doi.org/10.9767/bcrec.15.2.7753.454-464
Attar T, Nouali F, Kibou Z, Benchadli A, Messaoudi B, Choukchou-Braham E, Choukchou-Braham N. Corrosion inhibition, adsorption and thermodynamic properties of 2-aminopyridine derivatives on the corrosion of carbon steel in sulfuric acid solution. Journal of Chemical Sciences 2021;133(4):109. https://doi.org/10.1007/s12039-021-01971-w
Dhaundiyal P, Bashir S, Sharma V, Kumar A. An investigation on mitigation of corrosion of mildsteel by Origanum vulgare in acidic medium. Bulletin of the Chemical Society of Ethiopia 2019;33(1):159-168. https://doi.org/10.4314/bcse.v33i1.16
Mourya P, Singh P, Tewari A, Rastogi R, Singh M. Relationship between structure and inhibition behaviour of quinolinium salts for mild steel corrosion: Experimental and theoretical approach. Corrosion Science 2015;95:71-87. https://doi.org/10.1016/j.corsci.2015.02.034
Attar T, Benchadli A, Mellal T, Dali-Youcef B, Choukchou-Braham E. Use of Experimental Designs to Evaluate the Influence of Methyl Green Dye as a Corrosion Inhibitor for Carbon Steel in Perchloric Acid. Malaysian Journal of Chemistry 2021;23(1):60-69. https://doi.org/10.55373/mjchem.v23i1.878
Popova A, Christov M, Vasilev A. Mono- and dicationic benzothiazolic quaternary ammonium bromides as mild steel corrosion inhibitors. Part III: Influence of the temperature on the inhibition process. Corrosion Science 2015;94:70-78. https://doi.org/10.1016/j.corsci.2015.01.039
Ostapenko G, Gloukhov P, Bunev A. Investigation of 2-cyclohexenylcyclohexanone as steel corrosion inhibitor and surfactant in hydrochloric acid. Corrosion Science 2014;82:265-270. https://doi.org/10.1016/j.corsci.2014.01.029
Özcan M, Toffoli D, Üstünel H, Dehri T. Insights into surface-adsorbate interactions in corrosion inhibition processes at the molecular level. Corrosion Science 2014;80:482-486. https://doi.org/10.1016/j.corsci.2013.11.062
Mobin M, Rizvi M, Olasunkanmi L, Ebenso E. Biopolymer from Tragacanth Gum as a Green Corrosion Inhibitor for Carbon Steel in 1 M HCl Solution. ACS Omega 2017;2(7):3997-4008. https://doi.org/10.1021/acsomega.7b00436
Chen T, Zeng D, Zhou S. Study of Polyaspartic Acid and Chitosan Complex Corrosion Inhibition and Mechanisms. Polish Journal of Environmental Studies 2018;27(4):1441-1448. https://doi.org/10.15244/pjoes/78245
Dagdag O, Safi Z, Hsissou R, Erramli H, El Bouchti M, Wazzan N, Guo L, Verma C, Ebenso E, El Harfi A. Epoxy pre-polymers as new and effective materials for corrosion inhibition of carbon steel in acidic medium: Computational and experimental studies. Scientific Reports 2019;9(1):1-14. https://doi.org/10.1038/s41598-019-48284-0
Valbon A, Neves M, Echevarria A. Anticorrosive Effect of PVP 40000 Against AISI 1020 Carbon Steel in HCl. Materials Research 2018;21(6):1-7. https://doi.org/10.1590/1980-5373-mr-2017-0847
Benchadli A, Attar T, Messaoudi B, Choukchou-Braham E. Polyvinylpyrrolidone as a Corrosion Inhibitor for Carbon Steel in a Perchloric Acid Solution: Effect of Structural Size. Hungarian Journal of Industry and Chemistry 2021;49(1):59-69. https://doi.org/10.33927/hjic-2021-08
Benchadli A, Attar T, Choukchou-Braham E. Inhibition of Carbon Steel Corrosion in Perchloric Acid Solution by Povidone Iodine. Physical Chemistry Research 2019;7(4):837-848. https://doi.org/10.22036/pcr.2019.198787.1665
Hsissou R, Abbout S, Seghiri R, Rehioui M, Berisha A, Erramli H, Assouag M, Elharfi A. Evaluation of corrosion inhibition performance of phosphorus polymer for carbon steel in [1 M] HCl: Computational studies (DFT, MC and MD simulations). Journal of Materials Research and Technology 2020;9(3):2691-2703. https://doi.org/10.1016/j.jmrt.2020.01.002
Branzoi F, Băran A, Ludmila A, Alexandrescu E. The inhibition action of some organic polymers on the corrosion carbon steel in acidic media. Chemical Papers 2020;74(12):4315-4335. https://doi.org/10.1007/s11696-020-01242-x
Farag A, Ismail A, Migahed M. Squid By-product Gelatin Polymer as an Eco-friendly Corrosion Inhibitor for Carbon Steel in 0.5 M H2SO4 Solution: Experimental, Theoretical, and Monte Carlo Simulation Studies. Journal of Bio- and Tribo-Corrosion 2019;6(1):16. https://doi.org/10.1007/s40735-019-0310-0
Abdallah M. Maltodextrin and Chitosan Polymers as Inhibitors for the Corrosion of Carbon Steel in 1.0 M Hydrochloric Acid. International Journal of Electrochemical Science 2020;15:5650-5663. https://doi.org/10.20964/2020.06.82
Attar T, Benchadli A, Choukchou-Braham E. Corrosion inhibition of carbon steel in perchloric acid by potassium iodide. International Journal of Advanced Chemistry 2019;7(1):35-41. https://doi.org/10.14419/ijac.v7i1.19651
Benchadli A, Attar T, Choukchou-Braham E. Corrosion inhibition of carbon steel (XC 38) in hydrochloric acid by potassium iodide. Journal of Advanced Research in Science and Technology 2018;5(2):834-844.
Tigori M, Kouyaté A, Kouakou V, Niamien P, Trokourey A. Inhibition Performance of Some Sulfonylurea on Copper Corrosion in Nitric Acid Solution Evaluated Theoretically by DFT Calculations. Open Journal of Physical Chemistry 2020;10(03):139-157. https://doi.org/10.4236/ojpc.2020.103008
Chugh B, Singh A, Thakur S, Pani B, Lgaz H, Chung I, Jha R, Ebenso E. Comparative Investigation of Corrosion-Mitigating Behavior of Thiadiazole-Derived Bis-Schiff Bases for Mild Steel in Acid Medium: Experimental, Theoretical, and Surface Study. ACS Omega 2020;5(23):13503-13520. https://doi.org/10.1021/acsomega.9b04274
Benhadria N, Messaoudi B, Attar T. The Study of the Correlation between the Detection Limit and the Energy Stability of Two Antimony Complexes by Means of Conceptual DFT. Malaysian Journal of Chemistry 2020;22(2):111-120.
Danaee I, Ramesh Kumar S, Rashvand Avei M, Vijayan M. Electrochemical and Quantum Chemical Studies on Corrosion Inhibition Performance of 2,2'-(2-Hydroxyethylimino)bis[N-(alphaalpha-dimethylphenethyl)-N-methylacetamide] on Mild Steel Corrosion in 1M HCl Solution. Materials Research 2020;23(2):1-16. https://doi.org/10.1590/1980-5373-mr-2018-0610
Gad E, Azzam E, Halim S. Theoretical approach for the performance of 4-mercapto-1-alkylpyridin-1-ium bromide as corrosion inhibitors using DFT. Egyptian Journal of Petroleum 2018;27(4):695-699. https://doi.org/10.1016/j.ejpe.2017.10.005
Benhadria N, Attar T, Messaoudi B. Understanding the Link Between the Detection Limit and the Energy Stability of Two Quercetin–Antimony Complexes by Means of Conceptual DFT. South African Journal of Chemistry 2020;73(1):120–124. https://doi.org/10.17159/0379-4350/2020/v73a17
Attar T, Messaoudi B, Benhadria N. DFT Theoretical Study of Some Thiosemicarbazide Derivatives with Copper. Chemistry & Chemical Technology 2020;14(1):20-25. https://doi.org/10.23939/chcht14.01.020
Musa A, Kadhum A, Mohamad A, Takriff M. Molecular dynamics and quantum chemical calculation studies on 4,4-dimethyl-3-thiosemicarbazide as corrosion inhibitor in 2.5M H2SO4. Materials Chemistry and Physics 2011;129(1-2):660-665. https://doi.org/10.1016/j.matchemphys.2011.05.010
Alaoui K, El Kacimi Y, Galai M, Serrar H, Touir R, Kaya S, Kaya C, Ebn Touhami M. New triazepine carboxylate derivatives: correlation between corrosion inhibition property and chemical structure. International Journal of Industrial Chemistry 2020;11(1):23-42. https://doi.org/10.1007/s40090-019-00199-5
Guo L, Safi Z, Kaya S, Shi W, Tüzün B, Altunay N, Kaya C. Anticorrosive Effects of Some Thiophene Derivatives Against the Corrosion of Iron: A Computational Study. Frontiers in Chemistry 2018;6:1-12. https://doi.org/10.3389/fchem.2018.00155
Attar T, Larabi L, Harek Y. Inhibition effect of potassium iodide on the corrosion of carbon steel (XC 38) in acidic medium. International Journal of Advanced Chemistry 2014;2(2):139-142. https://doi.org/10.14419/ijac.v2i2.3272
Okechukwu Dominic O, Valentine Chikaodili A, Chizoba Sandra O. Optimum prediction for inhibition efficiency of Sapium ellipticum leaf extract as corrosion inhibitor of aluminum alloy (AA3003) in hydrochloric acid solution using electrochemical impedance spectroscopy and response surface methodology. Bulletin of the Chemical Society of Ethiopia 2020;34(1):175-191. https://doi.org/10.4314/bcse.v34i1.17
Attar T, Larabi L, Harek Y. Corrosion inhibition of cold rolled steel in 0.5M H2SO4 by potassium iodide. Der Pharma Chemica 2014;6(4):181-186.
El Faydy M, Lakhrissi B, Jama C, Zarrouk A, Olasunkanmi L, Ebenso E, Bentiss F. Electrochemical, surface and computational studies on the inhibition performance of some newly synthesized 8-hydroxyquinoline derivatives containing benzimidazole moiety against the corrosion of carbon steel in phosphoric acid environment. Journal of Materials Research and Technology 2020;9(1):727-748. https://doi.org/10.1016/j.jmrt.2019.11.014
Noor E, Al-Moubaraki A. Thermodynamic study of metal corrosion and inhibitor adsorption processes in mild steel/1-methyl-4[4′(-X)-styryl pyridinium iodides/hydrochloric acid systems. Materials Chemistry and Physics 2008;110(1):145-154. https://doi.org/10.1016/j.matchemphys.2008.01.028
Attar T, Benchadli A, Choukchou-Braham E. Inhibition of corrosion of copper by polyvinylpyrrolidone-iodine in sulfuric acid medium. Algerian Journal of Materials Chemistry 2022;5(1):1-8. https://doi.org/10.5281/zenodo.5855835
Sahrane M, Ghailane T, Galai M, Souizi A, Touhami M, Ghailane R, Touir R. Experimental and Theoretical Studies for Mild Steel Corrosion Inhibition in 1.0 M HCl by Two Stereoisomers of Benzothiazinone Derivatives. Portugaliae Electrochimica Acta 2020;38(1):1-17. https://doi.org/10.4152/pea.202001001
Faiz M, Zahari A, Awang K, Hussin H. Corrosion inhibition on mild steel in 1 M HCl solution by Cryptocarya nigra extracts and three of its constituents (alkaloids). RSC Advances 2020;10(11):6547-6562. https://doi.org/10.1039/c9ra05654h
Copyright (c) 2022 French-Ukrainian Journal of Chemistry
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Authors who publish with this journal agree to the following terms:
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).