Method for Calculation of the Current Concentration of Alkali in the Electrolyte During the Water Electrolysis Process
DOI:
https://doi.org/10.17721/fujcV9I2P27-33Keywords:
water electrolysis, electrolyte, alkali concentration, electrical conductivityAbstract
The article proposes a method for calculation of the current concentration of alkali in the electrolyte, taking into account the consumption and replenishment of feed water in the electrolyzer, which allows to estimate the specific electrical conductivity of the electrolyte during electrolysis process. This is important to increase the efficiency of the water electrolysis process. The calculated change of the current concentration of alkali in the electrolyte in high-pressure electrolyzers taking into account the volume of produced hydrogen is given. With the usage of the proposed method, it is established that the current concentrations of alkali in the electrolyte during the operation of the developed high-pressure electrolyzers are in the range of optimal concentrations, where the specific electrical conductivity of the electrolyte is close to maximum and changes according to alkali concentration change.
References
Miller H, Bouzek K, Hnat J, Loos S, Bernäcker C, Weißgärber T, Röntzsch L, Meier-Haack J. Green hydrogen from anion exchange membrane water electrolysis: a review of recent developments in critical materials and operating conditions. Sustainable Energy & Fuels 2020;4(5):2114-2133. https://doi.org/10.1039/c9se01240k
Rozzi E, Minuto F, Lanzini A, Leone P. Green Synthetic Fuels: Renewable Routes for the Conversion of Non-Fossil Feedstocks into Gaseous Fuels and Their End Uses. Energies 2020;13(2):420. https://doi.org/10.3390/en13020420
IRENA (2020), Green Hydrogen Cost Reduction: Scaling up Electrolysers to Meet the 1.5⁰C Climate Goal, International Renewable Energy Agency, Abu Dhabi. https://irena.org/-/media/Files/IRENA/Agency/Publication/2020/Dec/IRENA_Green_hydrogen_cost_2020.pdf.
Green Hydrogen from Water Electrolysis, Solution for Sustainability. Energy Industry Review. July 1, 2020. https://energyindustryreview.com/energy-efficiency/green-hydrogen-from-water-electrolysis-solution-for-sustainability/
Renee Cho. Why We Need Green Hydrogen. Columbia Climate School January 7, 2021. https://news.climate.columbia.edu/2021/01/07/need-green-hydrogen/
Duke researchers boost electrolyzer productivity with microfibrous flow-through electrode; 12.5- to 50-times greater than conventional. Green Car Congress. 01 June 2020. https://www.greencarcongress.com/2020/06/20200601-duke.html
Colli A, Girault H, Battistel A. Non-Precious Electrodes for Practical Alkaline Water Electrolysis. Materials 2019;12(8):1336. https://doi.org/10.3390/ma12081336
Yang F, Kim M, Brown M, Wiley B. Alkaline Water Electrolysis at 25 A cm−2 with a Microfibrous Flow‐through Electrode. Advanced Energy Materials 2020;10(25):2001174. https://doi.org/10.1002/aenm.202001174
Ulleberg O, Hancke R. Techno-economic calculations of small-scale hydrogen supply systems for zero emission transport in Norway. International Journal of Hydrogen Energy. 2020;45(2):1201–1211. https://doi.org/10.1016/j.ijhydene.2019.05.170
Li D, Park E, Zhu W, Shi Q, Zhou Y, Tian H, Lin Y, Serov A, Zulevi B, Baca E, Fujimoto C, Chung H, Kim Y. Highly quaternized polystyrene ionomers for high performance anion exchange membrane water electrolysers. Nature Energy 2020;5(5):378-385. https://doi.org/10.1038/s41560-020-0577-x
Yates J, Daiyan R, Patterson R, Amal R, Chang N. Techno-economic analysis of PV driven Hydrogen electrolysis - key drivers to economic feasibility. Australian PV Institute. 2019. http://apvi.org.au/solar-research-conference/proceedings-apsrc-2019/
Le Bideau D, Mandin P, Benbouzid M, Kim M, Sellier M. Review of necessary thermophysical properties and their sensivities with temperature and electrolyte mass fractions for alkaline water electrolysis multiphysics modelling. International Journal of Hydrogen Energy 2019;44(10):4553-4569. https://doi.org/10.1016/j.ijhydene.2018.12.222
Solovey V, Zipunnikov M, Semikin V. Method for Calculating the Feed Water Replenishment Parameters under Electrolysis Process in Electrolyzer. French-Ukrainian Journal of Chemistry 2020;8(2):168-175. https://doi.org/10.17721/fujcv8i2p168-175
Hamburg DYu, Dubovkin NF. Hydrogen. Properties, receipt, storage, transportation, application. Chemistry, 1989. 672 p.
Solovei V, Kotenko A, Vorobiova I, Shevchenko A, Zipunnikov M. Basic Operation Principles and Control Algorithm for a High-pressure Membrane-less Electrolyser. Journal of Mechanical Engineering 2018;21(4):57-63. https://doi.org/10.15407/pmach2018.04.057
Solovey V, Shevchenko A, Zipunnikov M, Kotenko A, Khiem N, Tri B, Hai T. Development of high pressure membraneless alkaline electrolyzer. International Journal of Hydrogen Energy 2021. In Press.https://doi.org/10.1016/j.ijhydene.2021.01.209
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