Development of Extraction Method of Polycyclic Aromatic Hydrocarbons from Sunflower Oil

Authors

  • Nataliya Tereshchenko Bogomolets National Medical University, Peremohy Ave., Kyiv 02000, Ukraine
  • Olena Khyzhan National University of Life and Environmental Sciences of Ukraine, Heroyiv Oborony st., 15, Kyiv - 03041, Ukraine
  • Lidia Kovshun National University of Life and Environmental Sciences of Ukraine, Heroyiv Oborony st., 15, Kyiv - 03041, Ukraine
  • Viktor Maksin National University of Life and Environmental Sciences of Ukraine, Heroyiv Oborony st., 15, Kyiv - 03041, Ukraine
  • Alexander Bobunov National University of Life and Environmental Sciences of Ukraine, Heroyiv Oborony st., 15, Kyiv - 03041, Ukraine

DOI:

https://doi.org/10.17721/fujcV8I2P7-16

Keywords:

polycyclic aromatic hydrocarbons, adsorption, activated charcoal, sunflower oil, chromatography

Abstract

Polycyclic aromatic hydrocarbons (PAHs) adsorption extraction process from sunflower oil on activated carbon was studied. Specific adsorption values on activated charcoal-xenobiotic system for compounds of benzo(a)anthracene, benzo(a)pyrene, benzo(e)pyrene, chrysene, benzo(b)fluoranthene and their mixtures were investigated. Influence of phase contact time of system, ratio of components on degree of PAHs extraction under isothermal conditions (25 ± 0.01ºC) was studied. Degree of oil purification was controlled by method of high performance liquid chromatography with fluorescence detector (HPLC/FLD). Leaning on patterns found, optimal conditions for purification of raw sunflower oil from PAHs using activated charcoal and obtaining the matrix of sunflower oil proposed.

Author Biographies

Nataliya Tereshchenko, Bogomolets National Medical University, Peremohy Ave., Kyiv 02000, Ukraine

Candidate of Chemical Science Associate Professor of Department of Medical and General Chemistry

Olena Khyzhan, National University of Life and Environmental Sciences of Ukraine, Heroyiv Oborony st., 15, Kyiv - 03041, Ukraine

Candidate of Chemical Science Associate Professor of Department of General, Organic and Physical Chemistry

Lidia Kovshun, National University of Life and Environmental Sciences of Ukraine, Heroyiv Oborony st., 15, Kyiv - 03041, Ukraine

Doctor of Technical Sciences Head of Department of General, Organic and Physical Chemistry

Viktor Maksin, National University of Life and Environmental Sciences of Ukraine, Heroyiv Oborony st., 15, Kyiv - 03041, Ukraine

Doctor of Chemical Science Professor of Department of Analytical and Bioinorganic Chemistry and Water Quality

Alexander Bobunov, National University of Life and Environmental Sciences of Ukraine, Heroyiv Oborony st., 15, Kyiv - 03041, Ukraine

Postgraduate, Department of Agrochemistry and Plant Production Quality

References

Hrybova N. Xenobiotics of PAHS group is extracted from sunflower seeds. Scientific Herald of National University of Life and Environmental Sciences of Ukraine. Series: Agronomy 2018;2018(294):209-2018. https://doi.org/10.31548/agr2018.294.209

Hrybova N. Xenobiotics of PAHS group is extracted from sunflower seeds. Scientific Herald of National University of Life and Environmental Sciences of Ukraine. Series: Agronomy 2018;2018(294):209-2018. https://doi.org/10.31548/agr2018.294.209

Grybova N, Nesterova L, Khyzhan O, Ushkalov V, Maksin V. Determination of Polycyclic Carbohydrates in Atmospheric Water by the Method of Chromatography. Journal of Water Chemistry and Technology 2018;40(5):297-301. https://doi.org/10.3103/s1063455x18050089

Gribova N, Filippenko T, Nikolaevskii A, Khizhan E, Bobyleva O. Effects of ultrasound on the extraction of antioxidants from bearberry (Arctostaphylos adans) leaves. Pharmaceutical Chemistry Journal 2008;42(10):593-595. https://doi.org/10.1007/s11094-009-0181-7

Hrybova NY. Vlijanie uslovij ekstrakcii na antioksidantnye svojstva izvlechennyh fitofenolov. Metody i ob"ekty himicheskogo analiza, 2012, (7,# 4), 202-206

Bysaha YeI, Olijnyk SV, Vyshnevska LI, Herasymova IV, Lytvynenko YeYu. Xromatohrafichni doslidzhennya olijnyx ekstraktiv z travy selery paxuchoyi ta pasternaku posivnoho, 2017.

Toxicological Review of Benzo[a]pyrene. Review of EPA’s Draft Assessment. U.S. Environmental Protection Agency. Washington: EPA, 2017. 97 р.

Huang Y, Zhou Q, Xie G. Development of micro-solid phase extraction with titanate nanotube array modified by cetyltrimethylammonium bromide for sensitive determination of polycyclic aromatic hydrocarbons from environmental water samples. Journal of Hazardous Materials 2011;193:82-89. https://doi.org/10.1016/j.jhazmat.2011.07.025

Sposib vydalennya policyklichnyx aromatychnyx vuhlevodniv. Ukraine patent 104865, 25.03.2014, Bul. № 6, 2014.

Sposib vyznachennya vmistu policyklichnyh aromatychnyh ta aromatychnyh vuhlevodniv u produktax, shho mistyat" harchovi oliyi ta zhyry. Ukraine patent 82364, 10.04.2008, Bul. № 7, 2008.

Koscevych NM. Vyznachennya antymikrobnoyi ta adsorbcijnoyi aktyvnosti vuhillya, zbahachenoho fitoekstraktamy. Problemy ekolohichnoyi biotexnolohiyi, 2015, (1).

Khrokalo L, , Pylypenko T, Verves K. Additional properties of pharmaceutical preparations: active coal and white coal. Naukovij vìsnik Nacìonalʹnogo unìversitetu bìoresursìv ì prirodokoristuvannâ Ukraïni. Serìâ Bìologìâ, bìotehnologìâ, ekologìâ 2018;2018(287):130-136. https://doi.org/10.31548/biologiya2018.287.130

Osejko MI. Теkhnologiya roslynnykh olii. Кiev: Vаrtа, 280.

DSTU EN 12915-1:2004, Materialy dlya ochyshhennya vody, pryznachenoyi dlya spozhyvannya lyudynoyu. Hranulovane aktyvovane vuhillya. Chastyna 1. Chyste hranulovane aktyvovane vuhillya. (EN 12915-1:2003, IDT)

Derun YuA et al. Rozrahunky parametriv hidrofobnosti izomeriv benzopirenu dlya poshuku optymal"nyh umov vymiryuvannya jih vmistu v atmosfernij vodi. Himichni problemy sohodennya, 2018, (S.l), p. 14. Available from: http://jhps.donnu.edu.ua/article/view/5159

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2020-12-22

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