Synthesis of 3-(2-Hydroxyphenyl)-5-(2-Pyridinyl)-1,2,4-triazoles as a potential chelate ligand for Uranyl ion

Authors

  • Oleksandr Vashchenko Taras Shevchenko National University of Kyiv
  • Dmytro Khomenko
  • Roman Doroschuk
  • Ilona Raspertova
  • Rostyslav Lampeka

DOI:

https://doi.org/10.17721/fujcV8I2P1-6

Keywords:

uranyl ion, 1, 2, 4-triazole, coordination compounds, NMR-spectroscopy

Abstract

Two new uranyl complexes with the molecular formula [(UO2)(H2L1)](СH3OH) and [(UO2)(H3L2)](СH3OH) {H4L1 = 2-[5-[[5-[[5-(2-pyridyl)-1H-1,2,4-triazol-3‑yl]methyl]-1H-1,2,4-triazol-3-yl]methyl]-1H-1,2,4-triazol-3-yl]phenol and H5L2 = 2-[5-[[5-[[5-[[5-(2-pyridyl)-1H-1,2,4‑triazol-3-yl]methyl]-1H-1,2,4-triazol-3-yl]methyl]-1H-1,2,4-triazol-3-yl]methyl]-1H-1,2,4-triazol-3-yl]phenol)} have been synthesized. All compounds have been characterized by NMR and IR spectroscopy. With H4L1 and H5L2 uranyl ion forms mononuclear complexes. In [(UO2)(H3L2)](СH3OH) pyridyl nitrogen was uncoordinated and bonding of H5L2 was realized only through phenol oxygen and N4-nitrogens of triazole cycles.


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Published

2020-12-22

Issue

Vol. 8 No. 2 (2020)

Section

Articles

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