Chemical grafting of sulfo groups onto carbon fibers

Liudmyla Grishchenko, Tetiana Bezugla, Anna Vakaliuk, Alexander Zaderko, Оleksandr Mischanchuk, Tetiana Zakharova, Olga Boldyrieva, Vitaliy Diyuk

Abstract

We proposed the brominated carbon cloth that made of polyacrylonitrile-based activated carbon fibers (PAN-ACFs) as a precursor to chemically and uniformly graft SO3H groups to prepare the solid acid catalyst. The thermal and catalytic properties of the sulfonated PAN-ACFs were examined by IR controlled catalytic measurements and thermal analysis. The catalytic test results showed that the sulfonated surface remarkably improved the operating efficiency in isopropanol dehydration by decreasing the reaction temperature. All PAN-ACFs with grafted SO3H groups prepared through brominated precursors can converse 100% of isopropanol into propylene at moderate temperature. They showed the highest catalytic activity compared to PAN-ACFs sulfonated with oleum and chlorosulfonic acid, which conversed only 40% and 70% of isopropanol into propylene and deactivated at the higher temperatures in the reaction medium.

Keywords

activated carbon fibers; surface modification; bromination; acidic groups; heterogeneous catalysts; isopropyl alcohol dehydration

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References

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