Increasing the efficiency Proton exchange membrane (PEMFC) & other fuel cells through multi graphene layers including polymer membrane electrolyte

Azin Chitsazan, Majid Monajjemi


Multi layers Graphene has been simulated theoretically for hydrogen storage and oxygen diffusion at a single unit of fuel cell. Ion transport rate of DFAFC, PAFC, AFC, PEMFC, DMFC and SOFC fuel cells have been studied. AFC which uses an aqueous alkaline electrolyte is suitable for temperature below 90 degree and is appropriate for higher current applications, while PEMFC is suitable for lower temperature compared to others.  Thermodynamic equations have been investigated for those fuel cells in viewpoint of voltage output data. Effects of operating data including temperature (T), pressure (P), proton exchange membrane water content (λ) , and proton exchange membrane thickness  on the optimal performance of the irreversible fuel cells have been studied.Obviously, the efficiency of PEMFC extremely related to amount of the H2 concentration, water activities in catalyst substrates and polymer of electrolyte membranes, temperature, and such variables dependence in the direction of the fuel and air streams.


PEM fuel cells; parameter modelling and simulation; graphene; Langmuir adsorption

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Ciureanu M. Effects of Nafion®Dehydration in PEM Fuel Cells. Journal of Applied Electrochemistry 2004;34(7):705-714.

Cruz-Manzo S, Chen R, Rama P. Study of current distribution and oxygen diffusion in the fuel cell cathode catalyst layer through electrochemical impedance spectroscopy. International Journal of Hydrogen Energy 2013;38(3):1702-1713.

de Bruijn F, Dam V, Janssen G. Review: Durability and Degradation Issues of PEM Fuel Cell Components. Fuel Cells 2008;8(1):3-22.

Larminie J, Dicks A. Fuel Cell Systems Explained. J. Wiley, 2003

Inc. Science Applications International Corporation Parsons. Fuel cell Handbook. U.S. Department of Energy, 2000

Kazmi I, Bhatti A, IqKazmi, I H, Bhatti A I, Iqbal S. A nonlinear observer for pem fuel cell system.Multitopic Conference, 2009, INMIC, 2009; IEEE 13th International, pages 1-6

U.S. Department of Energy. Hydrogen Data Book , 2017. Accessed on March 17th, 2017.

Litster S, McLean G. PEM fuel cell electrodes. Journal of Power Sources 2004;130(1-2):61-76.

Schmittinger W, Vahidi A. A review of the main parameters influencing long-term performance and durability of PEM fuel cells. Journal of Power Sources 2008;180(1):1-14.

Borup R, Meyers J, Pivovar B, Kim Y, Mukundan R, Garland N, Myers D, Wilson M, Garzon F, Wood D, Zelenay P, More K, Stroh K, Zawodzinski T, Boncella J, McGrath J, Inaba M, Miyatake K, Hori M, Ota K, Ogumi Z, Miyata S, Nishikata A, Siroma Z, Uchimoto Y, Yasuda K, Kimijima K, Iwashita N, . Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation. Chemical Reviews 2007;107(10):3904-3951.

Fly A. Thermal and water management of evaporatively cooled fuel cell vehicles. PhD Fly A. Thermal and water management of evaporatively cooled fuel cell vehicles. PhD thesis, Loughborough University, UK, 2015.

Zawodzinski T. Water Uptake by and Transport Through Nafion® 117 Membranes. Journal of The Electrochemical Society 1993;140(4):1041.

SU A, WENG F, HSU C, CHEN Y. Studies on flooding in PEM fuel cell cathode channels. International Journal of Hydrogen Energy 2006;31(8):1031-1039.

Pasaogullari U, Wang C. Two-Phase Modeling and Flooding Prediction of Polymer Electrolyte Fuel Cells. Journal of The Electrochemical Society 2005;152(2):A380.

Futerko P, Hsing I. Two-dimensional finite-element method study of the resistance of membranes in polymer electrolyte fuel cells. Electrochimica Acta 2000;45(11):1741-1751.

Dutta S, Shimpalee S, Van Zee J. . Journal of Applied Electrochemistry 2000;30(2):135-146.

Wang Z, Wang C, Chen K. Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells. Journal of Power Sources 2001;94(1):40-50.

He W, Lin G, Van Nguyen T. Diagnostic tool to detect electrode flooding in proton-exchange-membrane fuel cells. AIChE Journal 2003;49(12):3221-3228.

Bosco A D P, Fronk M H, Fuel cell flooding detection and correction, 2000. US Patent 6,103,409.

Le Canut J, Abouatallah R, Harrington D. Detection of Membrane Drying, Fuel Cell Flooding, and Anode Catalyst Poisoning on PEMFC Stacks by Electrochemical Impedance Spectroscopy. Journal of The Electrochemical Society 2006;153(5):A857.

Ciureanu M. Effects of Nafion®Dehydration in PEM Fuel Cells. Journal of Applied Electrochemistry 2004;34(7):705-714.

Frano Barbir. PEM Fuel Cells: Theory and Practice. Academic Press, 2005

Andrew Hamnett Carl H Hammann and Wolf Vielstich. Electrochemestry, WileyVCH, 2007

Rowe A, Li X. Mathematical modeling of proton exchange membrane fuel cells. Journal of Power Sources 2001;102(1-2):82-96.

Siegel C. Review of computational heat and mass transfer modeling in polymer-electrolyte-membrane (PEM) fuel cells. Energy 2008;33(9):1331-1352.

Yao K, Karan K, McAuley K, Oosthuizen P, Peppley B, Xie T. A Review of Mathematical Models for Hydrogen and Direct Methanol Polymer Electrolyte Membrane Fuel Cells. Fuel Cells 2004;4(12):3-29.

Pukrushpan J, Peng H, Stefanopoulou A. Control-Oriented Modeling and Analysis for Automotive Fuel Cell Systems. Journal of Dynamic Systems, Measurement, and Control 2004;126(1):14-25.

Tao W, Min C, Liu X, He Y, Yin B, Jiang W. Parameter sensitivity examination and discussion of PEM fuel cell simulation model validation. Journal of Power Sources 2006;160(1):359-373.

Karimi G, Jamekhorshid A, Azimifar Z, Li X. Along-channel flooding prediction of polymer electrolyte membrane fuel cells. International Journal of Energy Research 2010;35(10):883-896.

Gurau V, Liu H, Kakaç S. Two-dimensional model for proton exchange membrane fuel cells. AIChE Journal 1998;44(11):2410-2422.

Schmidt M, Baldridge K, Boatz J, Elbert S, Gordon M, Jensen J, Koseki S, Matsunaga N, Nguyen K, Su S, Windus T, Dupuis M, Montgomery J. General atomic and molecular electronic structure system. Journal of Computational Chemistry 1993;14(11):1347-1363.

Zhao Y, Truhlar D. The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals. Theoretical Chemistry Accounts 2007;120(1-3):215-241.

Ao Z, Yang J, Li S, Jiang Q. Enhancement of CO detection in Al doped graphene. Chemical Physics Letters 2008;461(4-6):276-279.

Perdew J, Burke K, Ernzerhof M. Generalized Gradient Approximation Made Simple. Physical Review Letters 1996;77(18):3865-3868.

Besler B, Merz K, Kollman P. Atomic charges derived from semiempirical methods. Journal of Computational Chemistry 1990;11(4):431-439.

Chirlian L, Francl M. Atomic charges derived from electrostatic potentials: A detailed study. Journal of Computational Chemistry 1987;8(6):894-905.

Breneman C, Wiberg K. Determining atom-centered monopoles from molecular electrostatic potentials. The need for high sampling density in formamide conformational analysis. Journal of Computational Chemistry 1990;11(3):361-373.