Catalytic efficiency of activated carbon functionalized with phosphorus-containing groups in 2-propanol dehydration

Liudmyla Grishchenko, Natalia Novychenko, Igor Matushko, Alexander Zaderko, Galyna Tsapyuk, Oleksandr Mischanchuk, Vitaliy Diyuk, Vladyslav Lisnyak

Abstract


The functionalization of activated carbon (AC) by P-containing groups was conducted, and their thermal desorption was studied. Depending on the used method, the functionalized AC contains 0.5–1.45 mmol/g of acidic groups acting in catalytic 2-propanol dehydration. All catalysts showed 100% conversion of 2-propanol to propylene. The catalytic activity does not change with time under isothermal conditions and during their repeated use in catalysis, for 3 cycles of heating-cooling. In fact, the yield of propylene remains stable; it does not decrease with each cycle. Preliminary oxidation with nitric acid causes a small increase in the catalytic activity.


Keywords


activated carbon; surface modification; acidic groups; heterogeneous catalysts; isopropyl alcohol dehydration

Full Text:

PDF

References


Veksha A, Sasaoka E, Uddin M. The influence of porosity and surface oxygen groups of peat-based activated carbons on benzene adsorption from dry and humid air. Carbon 2009;47(10):2371-2378. https://doi.org/10.1016/j.carbon.2009.04.028

Wang T, Tan S, Liang C. Preparation and characterization of activated carbon from wood via microwave-induced ZnCl2 activation. Carbon 2009;47(7):1880-1883. https://doi.org/10.1016/j.carbon.2009.03.035

Bagreev A, Angel Menendez J, Dukhno I, Tarasenko Y, Bandosz T. Bituminous coal-based activated carbons modified with nitrogen as adsorbents of hydrogen sulfide. Carbon 2004;42(3):469-476. https://doi.org/10.1016/j.carbon.2003.10.042

Bedia J, Barrionuevo R, Rodríguez-Mirasol J, Cordero T. Ethanol dehydration to ethylene on acid carbon catalysts. Applied Catalysis B: Environmental 2011;103(3-4):302-310. https://doi.org/10.1016/j.apcatb.2011.01.032

Dias J, Alvim-Ferraz M, Almeida M, Rivera-Utrilla J, Sánchez-Polo M. Waste materials for activated carbon preparation and its use in aqueous-phase treatment: A review. Journal of Environmental Management 2007;85(4):833-846. https://doi.org/10.1016/j.jenvman.2007.07.031

Angin D. Production and characterization of activated carbon from sour cherry stones by zinc chloride. Fuel 2014;115:804-811. https://doi.org/10.1016/j.fuel.2013.04.060

Kütahyalı C, Eral M. Sorption studies of uranium and thorium on activated carbon prepared from olive stones: Kinetic and thermodynamic aspects. Journal of Nuclear Materials 2010;396(2-3):251-256. https://doi.org/10.1016/j.jnucmat.2009.11.018

Bedia J, Ruiz-Rosas R, Rodríguez-Mirasol J, Cordero T. Kinetic study of the decomposition of 2-butanol on carbon-based acid catalyst. AIChE Journal 2009;56(6):1557-1568. https://doi.org/10.1002/aic.12056

Diyuk V, Zaderko A, Grishchenko L, Yatsymyrskiy A, Lisnyak V. Efficient carbon-based acid catalysts for the propan-2-ol dehydration. Catalysis Communications 2012;27:33-37. https://doi.org/10.1016/j.catcom.2012.06.018

Toda M, Takagaki A, Okamura M, Kondo J, Hayashi S, Domen K, Hara M. Biodiesel made with sugar catalyst. Nature 2005;438(7065):178-178. https://doi.org/10.1038/438178a

Sun J, Wu L, Wang Q. Comparison about the structure and properties of PAN-based activated carbon hollow fibers pretreated with different compounds containing phosphorus. Journal of Applied Polymer Science 2005;96(2):294-300. https://doi.org/10.1002/app.21385

Ternero-Hidalgo J, Rosas J, Palomo J, Valero-Romero M, Rodríguez-Mirasol J, Cordero T. Functionalization of activated carbons by HNO 3 treatment: Influence of phosphorus surface groups. Carbon 2016;101:409-419. https://doi.org/10.1016/j.carbon.2016.02.015

Hulicova-Jurcakova D, Puziy A, Poddubnaya O, Suárez-García F, Tascón J, Lu G. Highly Stable Performance of Supercapacitors from Phosphorus-Enriched Carbons. Journal of the American Chemical Society 2009;131(14):5026-5027. https://doi.org/10.1021/ja809265m

Bedia J, Rosas J, Márquez J, Rodríguez-Mirasol J, Cordero T. Preparation and characterization of carbon based acid catalysts for the dehydration of 2-propanol. Carbon 2009;47(1):286-294. https://doi.org/10.1016/j.carbon.2008.10.008

Bedia J, Rosas J, Vera D, Rodríguez-Mirasol J, Cordero T. Isopropanol decomposition on carbon based acid and basic catalysts. Catalysis Today 2010;158(1-2):89-96. https://doi.org/10.1016/j.cattod.2010.04.043

Soleimani M, Kaghazchi T. Agricultural Waste Conversion to Activated Carbon by Chemical Activation with Phosphoric Acid. Chemical Engineering & Technology 2007;30(5):649-654. https://doi.org/10.1002/ceat.200600325

Multian V, Kinzerskyi F, Vakaliuk A, Grishchenko L, Diyuk V, Boldyrieva O, Kozhanov V, Mischanchuk O, Lisnyak V, Gayvoronsky V. Surface Response of Brominated Carbon Media on Laser and Thermal Excitation: Optical and Thermal Analysis Study. Nanoscale Research Letters 2017;12(1):. https://doi.org/10.1186/s11671-017-1873-7

Grishchenko L, Vakaliuk A, Diyuk V, Boldyrieva O, Lisnyak V, Radkevich V, Mischanchuk O. Functionalization of surface layer of nanoporous carbon fibers with bromine and amine functional groups. 2017 IEEE 7th International Conference Nanomaterials: Application & Properties (NAP) 2017;:. https://doi.org/10.1109/nap.2017.8190155

Diyuk V, Mariychuk R, Lisnyak V. Barothermal preparation and characterization of micro-mesoporous activated carbons. Journal of Thermal Analysis and Calorimetry 2016;124(2):1119-1130. https://doi.org/10.1007/s10973-015-5208-6

Diyuk V, Mariychuk R, Lisnyak V. Functionalization of activated carbon surface with sulfonated styrene as a facile route for solid acids preparation. Materials Chemistry and Physics 2016;184:138-145. https://doi.org/10.1016/j.matchemphys.2016.09.034

Bezugla T, Grishchenko L, Vakaliuk A, Diyuk V, Mischanchuk O, Lisnyak V. Covalent bonding of sulfogroups to activated carbon fibers: The role of bromine plasma pretreatment. Molecular Crystals and Liquid Crystals 2018;661(1):58-67. https://doi.org/10.1080/15421406.2018.1460240

Diyuk V, Gorlova A, Grishchenko L, Chernyavskaya T, Yatsimirskii V. Kinetics of the gas-phase chlorination of activated carbon with carbon tetrachloride. Theoretical and Experimental Chemistry 2011;47(4):264-269. https://doi.org/10.1007/s11237-011-9214-x

Grishchenko LM, Blyzniuk BV, Diyuk VE and et.al. Adsorption Characteristics of Nanoporous Activated Carbon Tailored with Acidic Treatment. Proceedings of the 2018 IEEE 8th International Conference on Nanomaterials: Applications and Properties (NAP).

Grishchenko L, Diyuk V, Konoplitska O, Lisnyak V, Maryichuk R. Modeling of copper ions adsorption onto oxidative-modified activated carbons. Adsorption Science & Technology 2017;35(9-10):884-900. https://doi.org/10.1177/0263617417729236




DOI: https://doi.org/10.17721/fujcV7I1P46-56

Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

ISSN 2312-3222 (Online)

Creative Commons License
 French-Ukrainian Journal of Chemistry is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

Copyright (c) 2013 French-Ukrainian Journal of Chemistry