Behaviour of Solid Oxide Fuel Cell Materials in Technological Environments

Authors

  • Viktoriya Podhurska Karpenko Physico-Mechanical Institute
  • Bogdan Vasyliv
  • Andrij Ivasyshyn
  • Orest Ostash
  • Oleksandr Vasylyev
  • Tetyana Prikhna
  • Volodymyr Sverdun
  • Yehor Brodnikovskyi

DOI:

https://doi.org/10.17721/fujcV6I1P115-127

Keywords:

solid oxide fuel cell (SOFC), YSZ–NiO anode ceramics, MAX-phase interconnect, reducing and oxidizing gas environments, physical and mechanical properties, structure

Abstract

The YSZ–NiO ceramics for SOFC anodes and MAX-phases of Ti-Al-C systems for interconnects have been investigated. Based on the tests of YSZ–NiO specimens preconditioned by one-time reduction or by redox cycling at 600 or 800 °C, a certain mode of the material treatment was established which provides its improved physicomechanical properties. The oxidation behaviour of MAX-phases has been investigated at 600 °C in air. It was found that the intense initial oxidation of hot-pressed Ti3AlC2-based material can be eliminated by a certain mode of pre-oxidation. The oxidation resistance of the material can be significantly improved by niobium addition.

References

Sarantaridis D, Atkinson A. Redox Cycling of Ni-Based Solid Oxide Fuel Cell Anodes: A Review. Fuel Cells 2007;7(3):246-258. https://doi.org/10.1002/fuce.200600028

Ettler M, Timmermann H, Malzbender J, Weber A, Menzler N. Durability of Ni anodes during reoxidation cycles. Journal of Power Sources 2010;195(17):5452-5467. https://doi.org/10.1016/j.jpowsour.2010.03.049

Wood A, Waldbillig D. Preconditioning treatment to enhance redox tolerance of solid oxide fuel cells. United States patent 20118029946 B2. 2011 Oct 4.

Podhurs’ka V, Vasyliv B, Ostash O, Vasyl’ev O, Brodnikovs’kyi E. Structural Transformations in the Nio-Containing Anode of Ceramic Fuel Cells in the Course of its Reduction and Oxidation. Materials Science 2014;49(6):805-811. https://doi.org/10.1007/s11003-014-9677-8

Ostash O, Vasyliv B, Podhurs’ka V, Vasyl’ev O, Brodnikovs’kyi E, Ushkalov L. Optimization of the properties of 10Sc1CeSZ–NiO composite by the redox treatment. Materials Science 2011;46(5):653-659. https://doi.org/10.1007/s11003-011-9337-1

Vasyliv B, Podhurs’ka V, Ostash O, Vasyl’ev �, Brodnikovs’kyi E. Influence of Reducing and Oxidizing Media on the Physicomechanical Properties of ScCeSZ–NiO and YSZ–NiO Ceramics. Materials Science 2013;49(2):135-144. https://doi.org/10.1007/s11003-013-9593-3

Radovic M, Barsoum MW (2013) MAX phases: bridging the gap between metals and ceramics. Amer Ceram Soc Bull 92(3):20–27

Barsoum M, Yoo H, Polushina I, Rud’ V, Rud’ Y, El-Raghy T. Electrical conductivity, thermopower, and Hall effect ofTi3AlC2,Ti4AlN3,andTi3SiC2. Physical Review B 2000;62(15):10194-10198. https://doi.org/10.1103/physrevb.62.10194

Prikhna T, Cabioc’h T, Gawalek W, Ostash O, Litzkendorf D, Dub S, Loshak M, Sverdun V, Chartier P, Basyuk T, Moshchil V, Kozyrev A, Karpets M, Kovylaev V, Starostina A, Turkrvich D. Study of the Thermal Stability and Mechanical Characteristics of MAX Phases of Ti-Al-C(N) System and their Solid Solutions. Advances in Science and Technology 2014;89:123-128. https://doi.org/10.4028/www.scientific.net/ast.89.123

Barsoum M, Tzenov N, Procopio A, El-Raghy T, Ali M. Oxidation of Ti[sub n+1]AlX[sub n] (n=1-3 and X=C, N): II. Experimental Results. Journal of The Electrochemical Society 2001;148(8):C551. https://doi.org/10.1149/1.1380256

Song G, Pei Y, Sloof W, Li S, De Hosson J, van der Zwaag S. Early stages of oxidation of Ti3AlC2 ceramics. Materials Chemistry and Physics 2008;112(3):762-768. https://doi.org/10.1016/j.matchemphys.2008.06.038

Wang X, Zhou Y. Oxidation behavior of Ti3AlC2 at 1000–1400 °C in air. Corrosion Science 2003;45(5):891-907. https://doi.org/10.1016/s0010-938x(02)00177-4

Ai T. High-temperature oxidation behavior of un-dense Ti3AlC2 material at 1000°C in air. Ceramics International 2012;38(3):2537-2541. https://doi.org/10.1016/j.ceramint.2011.10.091

Wang X, Zhou Y. Oxidation behavior of TiC-containing Ti3AlC2 based material at 500–900 °C in air. Materials Research Innovations 2003;7(6):381-390. https://doi.org/10.1007/s10019-003-0278-7

Pang W, Low I, O’Connor B, Sun Z, Prince K. Oxidation characteristics of Ti3AlC2 over the temperature range 500–900°C. Materials Chemistry and Physics 2009;117(2-3):384-389. https://doi.org/10.1016/j.matchemphys.2009.06.016

Podhurska V, Vasyliv B. Influence of redox treatment temperature on microstructure and properties of Ni-ZrO2 anode materials. International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014) 2014;:. https://doi.org/10.1109/omee.2014.6912353

Tikekar N, Armstrong T, Virkar A. Reduction and Reoxidation Kinetics of Nickel-Based SOFC Anodes. Journal of The Electrochemical Society 2006;153(4):A654. https://doi.org/10.1149/1.2167949

Akselrud L, Zavalii P, Grin Y, Pecharski V, Baumgartner B, Wölfel E. Use of the CSD Program Package for Structure Determination from Powder Data. Materials Science Forum 1993;133-136:335-342. https://doi.org/10.4028/www.scientific.net/msf.133-136.335

Sun B, Rudkin R, Atkinson A. Effect of Thermal Cycling on Residual Stress and Curvature of Anode-Supported SOFCs. Fuel Cells 2009;9(6):805-813. https://doi.org/10.1002/fuce.200800133

Mills I, Cvitas T, Homann K et al. Quantities, units and symbols in physical chemistry. Oxford: BLACKWELL SCIENCE LTD.; 1993, pp.1-165.

Peraldi R, Monceau D, Pieraggi B. . Oxidation of Metals 2002;58(3/4):249-273. https://doi.org/10.1023/a:1020170320020

Faes A, Nakajo A, Hessler-Wyser A, Dubois D, Brisse A, Modena S, Van herle J. RedOx study of anode-supported solid oxide fuel cell. Journal of Power Sources 2009;193(1):55-64. https://doi.org/10.1016/j.jpowsour.2008.12.118

ZHANG Y, LIU B, TU B, DONG Y, CHENG M. Redox cycling of Ni–YSZ anode investigated by TPR technique. Solid State Ionics 2005;176(29-30):2193-2199. https://doi.org/10.1016/j.ssi.2005.06.016

Mori M. Thermal Expansion of Nickel-Zirconia Anodes in Solid Oxide Fuel Cells during Fabrication and Operation. Journal of The Electrochemical Society 1998;145(4):1374. https://doi.org/10.1149/1.1838468

Wang X, Zhou Y. Improvement of intermediate-temperature oxidation resistance of Ti3AIC2 by pre-oxidation at high temperatures. Materials Research Innovations 2003;7(4):205-211. https://doi.org/10.1007/s10019-003-0252-4

Barsoum M, . Oxidation Of Ti[sub 3]SiC[sub 2] in Air. Journal of The Electrochemical Society 1997;144(7):2508. https://doi.org/10.1149/1.1837846

Jiang H, Hirohasi M, Lu Y, Imanari H. Effect of Nb on the high temperature oxidation of Ti–(0–50 at.%)Al. Scripta Materialia 2002;46(9):639-643. https://doi.org/10.1016/s1359-6462(02)00042-8

Downloads

Published

2018-07-24

Issue

Vol. 6 No. 1 (2018): Hydrogen energy: towards better materials for higher efficiency

Section

Articles

License

Copyright (c) 2018 French-Ukrainian Journal of Chemistry

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The French‑Ukrainian Journal of Chemistry holds copyright and publishes all articles under a Creative Commons Attribution 4.0 International licence (CC BY 4.0).
This license permits unrestricted use, sharing, adaptation, distribution, and reproduction in any medium or format, provided that the original author(s) and source are credited, a link to the license is included, and any changes made are indicated.
Authors grant the French‑Ukrainian Journal of Chemistry the exclusive right of first publication and may enter into separate, non‑exclusive distribution agreements for the published version (e.g., institutional repository, book chapter). Authors are also encouraged to post pre‑prints and post‑prints online to increase visibility and citation.