The interaction of homophthalic anhydride with (triphenylphosphoranylidene)acetates

Oleh Valentinovich Shablykin, Daniil Merzhyievsky, Olga Shablykina

Abstract


In the study of the interaction of homo­phthalic anhydride and methyl (triphenyl­phosphoranylidene)­acetate, along with (1-oxo-1H-isochromen-3‑yl)acetate obtaining, two minor products – (1,3-dioxo-1,2,3,4-tetrahydronaphthalene-2-yl)acetate and 2‑((1‑oxo-1H-isochromen-3-yl)methyl)benzoic acid – had been isolated. The action of tert‑butyl (triphenyl­phosphoranylidene)­acetate on homo­phthalic anhydride didn’t lead to Wittig reaction; the encumbered ylide demonstrated only its basicity, and products of homo­phthalic anhydride self-condensation – 2‑((1‑oxo-1H-isochromen-3-yl)methyl)-benzoic acid and 12-hydroxy-5H-dibenzo[c,g]chromen-5-one – were formed.

Keywords


homophthalic anhydride; (triphenylphosphoranylidene)acetates; Wittig reaction; self-condensation of homophthalic anhydride

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References


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DOI: https://doi.org/10.17721/fujcV5I2P62-67

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