First example of ring carbomer of 1,4-cyclohexadiene

Authors

  • Cécile Barthes CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France Université de Toulouse, UPS, ICT-FR 2599, 31062 Toulouse Cedex 9, France.
  • Arnaud Rives CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France Université de Toulouse, UPS, ICT-FR 2599, 31062 Toulouse Cedex 9, France.
  • Valérie Maraval CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France Université de Toulouse, UPS, ICT-FR 2599, 31062 Toulouse Cedex 9, France.
  • Evelyne Chelain EA 4505, LCB (Laboratoire de Chimie Biologique), 5 mail Gay Lussac - Neuville sur Oise, F-95031 Cergy Pontoise Cedex, France
  • Thierry Brigaud EA 4505, LCB (Laboratoire de Chimie Biologique), 5 mail Gay Lussac - Neuville sur Oise, F-95031 Cergy Pontoise Cedex, France
  • Remi Chauvin CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France Université de Toulouse, UPS, ICT-FR 2599, 31062 Toulouse Cedex 9, France.

DOI:

https://doi.org/10.17721/fujcV3I1P60-65

Keywords:

butatrienes, carbo-cyclohexadienes, carbo-mers, nucleophilic trifluoromethylation

Abstract


While a series of carbo-mers of 1,3-cyclohexadienes was reported through the use of a specifically developed synthetic strategy, no example of their 1,4-regioisomers was known. Inspired by the methodology elaborated for the preparation of the 1,3-isomers, the synthesis of the first example of carbo-mer of 1,4-cyclohexadiene is presented. Comparison of physico-chemical properties of this first representative with those of the recently described 1,4-regioisomer, especially UV-vis absorption properties, is also addressed.

References

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2015-03-10

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