In situ polymerization of 4-(methacryloylamino) phenyl-2-methylacrylate on the surface of silicagel

Authors

  • Elina Yanovska Chemistry Department, Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine
  • Lyudmyla Vretik Chemistry Department, Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine
  • Dariusz Sternik Maria Curie-Skłodowska University, 2 Maria Curie-Skłodowska Sq., 20 031 Lublin, Poland
  • Olga Kychkiruk Department of Sciences, Ivan Franko Zhytomyr State University, 40 Velyka Berdychivska St., 10008 Zhytomyr, Ukraine
  • Olena Nikolaeva Chemistry Department, Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine
  • Iana Buriachenko Chemistry Department, Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine

DOI:

https://doi.org/10.17721/fujcV4I2P47-54

Keywords:

phenylmethylacrylate, modified silica, in situ immobilization, metal complexes, adsorption properties

Abstract

Immobilization of 4-(methacryloylamino)phenyl-2-methylacrylate homopolymer on the silica gel surface has been carried out in situ. The structure and quantitative characteristics of immobilized polymer have been examined by IR spectroscopy, thermogravimetric analysis and mass spectrometry. Adsorption activity towards microquantitatives of Pb(II), Cu (II), Mn(II), Co(II), Ni(II) and Fe(III) ions in the range of pH 6-8,5 has been observed. Quantitative adsorption of trace Pb(II) in neutral and slightly alkaline media has been reported.

Author Biography

Lyudmyla Vretik, Chemistry Department, Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine

Chemistry department

References

Zaitsev VN. Complexing silica: synthesis, structure of the graft layer and surface chemistry. Kharkov Ukraine: Folio; 1997.

Lisichkin GV, Fadeev AY, Serdan AA et al, Chemistry grafted surface compounds, Moscow, Russia: FIZMATLIT; 2003.

Tertykh V, Polishchuk L, Yanishpolskii V, Yanovska E, Dadashev A, Karmanov V, Kichkiruk O. Adsorption Properties of Functional Silicas Towards Some Toxic Metal Ions in Water Solutions. NATO Science for Peace and Security Series C: Environmental Security 2008;:119-132. https://doi.org/10.1007/978-1-4020-6805-8_11

Yanovska ES, Dadashev AD, Tertykh VA. Inorganic anion-exchanger based on silica with grafted polyhexamethyleneguanidine hydrochloride. Func. Mat. 2009;16(1):105-9.

Dadashev AD, Tertykh VA, Yanovska ES, Yanova KV. Ion-Exchange Properties of Modified Silica with Bound Amides of Polyhexamethyleneguanidine and Maleic or o-Phthalic Acids Chem. Phys. and Tech. of Surf. 2012;3(4):419-28.

Yanovska ES, Ryabchenko KV, Tertykh VA, Kichkiruk OYu. Chem. Phys. and Tech. of Surf., 2012;3(4):439-45.

Pascal LP, Ph.D. Thesis, Kyiv,Ukraine, 1984 (in Ukrainian).

Nіkolaeva OA, Ph.D. Thesis, Kyiv,Ukraine, 2011 (in Ukrainian).

Anderson JC, Reese CB. Photo-Induced Fries Rearrangements. Proceedings of the Chemical Society. June 1960. Proceedings of the Chemical Society 1960;(June):217. https://doi.org/10.1039/ps9600000193

Frechet J, Tessier T, Willson C, Ito H. Poly[p-(formyloxy)styrene]: synthesis and radiation-induced decarbonylation. Macromolecules 1985;18(3):317-321. https://doi.org/10.1021/ma00145a002

Li S, Guillet J. Studies of the Photo-Fries Reaction in Solid Poly(phenyl acrylate). Macromolecules 1977;10(4):840-844. https://doi.org/10.1021/ma60058a023

Merle-Aubry L, Holden D, Merle Y, Guillet J. Photophysics and Photochemistry of Naphthly Ester Polymers in Solution. Macromolecules 1980;13(5):1138-1143. https://doi.org/10.1021/ma60077a021

Höfler T, Grießer T, Gstrein X, Trimmel G, Jakopic G, Kern W. UV reactive polymers for refractive index modulation based on the photo-Fries rearrangement. Polymer 2007;48(7):1930-1939. https://doi.org/10.1016/j.polymer.2007.01.041

Griesser T, Höfler T, Temmel S, Kern W, Trimmel G. Photolithographic Patterning of Polymer Surfaces Using the Photo-Fries Rearrangement: Selective Postexposure Reactions. Chemistry of Materials 2007;19(12):3011-3017. https://doi.org/10.1021/cm070506h

Daschiel U, Höfler T, Jakopic G, Schmidt V, Kern W. Selected Polymers that Contain Aromatic Ester Units: Synthesis, Photoreactions, and Refractive Index Modulation. Macromolecular Chemistry and Physics 2007;208(11):1190-1201. https://doi.org/10.1002/macp.200700035

Vretik L, Syromyatnikov V, Zagniy V, Savchuk E, Yaroshchuk O. Problem of Photoalignment in the LCD's Development: Synthetic Routes in Its Solving. Molecular Crystals and Liquid Crystals 2008;486(1):57/[1099]-65/[1107]. https://doi.org/10.1080/15421400801917395

Gunzler H, Gremlich H-U. IR Spectroscopy. An introduction. Weinheim: Wiley-VCH Verlag Gmbh & Co.; 2002, pp.60-2.

Parfitt GD, Rochester CH. Adsorption from solution at the solid/liquid interface. Moscow, Russia: Mir; 1986.

Skopenko VV, Saranskiy LI. Coordination chemistry. Kyiv, Ukraine: Lybid, 2004 (in Ukrainian).

Downloads

Published

2016-12-27

Issue

Vol. 4 No. 2 (2016)

Section

Articles

License

Authors who publish with this journal agree to the following terms:

  • Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

  • Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.

  • Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).